Llwytho...
Direct and enantioselective α-allylation of ketones via singly occupied molecular orbital (SOMO) catalysis
The first enantioselective organocatalytic α-allylation of cyclic ketones has been accomplished via singly occupied molecular orbital catalysis. Geometrically constrained radical cations, forged from the one-electron oxidation of transiently generated enamines, readily undergo allylic alkylation wit...
Wedi'i Gadw mewn:
| Prif Awduron: | , , , |
|---|---|
| Fformat: | Artigo |
| Iaith: | Inglês |
| Cyhoeddwyd: |
National Academy of Sciences
2010
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| Pynciau: | |
| Mynediad Ar-lein: | https://ncbi.nlm.nih.gov/pmc/articles/PMC2996445/ https://ncbi.nlm.nih.gov/pubmed/20921367 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1073/pnas.1002845107 |
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