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Oxy-Allyl Cation Catalysis: An Enantioselective Electrophilic Activation Mode
A generic activation mode for asymmetric LUMO-lowering catalysis has been developed using the long-established principles of oxy-allyl cation chemistry. Here, the enantioselective conversion of racemic α-tosyloxy ketones to optically enriched α-indolic carbonyls has been accomplished using a new ami...
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| Publicat a: | J Am Chem Soc |
|---|---|
| Autors principals: | , , , , , |
| Format: | Artigo |
| Idioma: | Inglês |
| Publicat: |
2016
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| Matèries: | |
| Accés en línia: | https://ncbi.nlm.nih.gov/pmc/articles/PMC5103282/ https://ncbi.nlm.nih.gov/pubmed/26797012 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.5b13041 |
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