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The Intramolecular Asymmetric Allylation of Aldehydes via Organo-SOMO Catalysis: A Novel Approach to Ring Construction

The intramolecular asymmetric cyclization of aldehydes has been accomplished using singly occupied molecular orbital (SOMO) catalysis. Selective oxidation of chiral enamines (formed by the condensation of an aldehyde and a secondary amine catalyst) leads to the formation of a 3π-electron radical spe...

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Detalhes bibliográficos
Main Authors: Pham, Phong V., Ashton, Kate, MacMillan, David W. C.
Formato: Artigo
Idioma:Inglês
Publicado em: 2011
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC3474369/
https://ncbi.nlm.nih.gov/pubmed/23087809
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/C1SC00176K
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