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The Intramolecular Asymmetric Allylation of Aldehydes via Organo-SOMO Catalysis: A Novel Approach to Ring Construction

The intramolecular asymmetric cyclization of aldehydes has been accomplished using singly occupied molecular orbital (SOMO) catalysis. Selective oxidation of chiral enamines (formed by the condensation of an aldehyde and a secondary amine catalyst) leads to the formation of a 3π-electron radical spe...

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Bibliografiske detaljer
Main Authors: Pham, Phong V., Ashton, Kate, MacMillan, David W. C.
Format: Artigo
Sprog:Inglês
Udgivet: 2011
Fag:
Online adgang:https://ncbi.nlm.nih.gov/pmc/articles/PMC3474369/
https://ncbi.nlm.nih.gov/pubmed/23087809
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/C1SC00176K
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