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A Nine-Step Enantioselective Total Synthesis of (−)-Vincorine
A concise and highly enantioselective total synthesis of the akuammiline alkaloid (−)-vincorine has been accomplished. A key element of the synthesis is a stereoselective organocatalytic Diels–Alder, iminium cyclization cascade sequence, which serves to construct the tetracyclic alkaloid core archit...
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| Main Authors: | , |
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| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2013
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC3667606/ https://ncbi.nlm.nih.gov/pubmed/23586842 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja402933s |
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