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A Nine-Step Enantioselective Total Synthesis of (−)-Vincorine

A concise and highly enantioselective total synthesis of the akuammiline alkaloid (−)-vincorine has been accomplished. A key element of the synthesis is a stereoselective organocatalytic Diels–Alder, iminium cyclization cascade sequence, which serves to construct the tetracyclic alkaloid core archit...

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Main Authors: Horning, Benjamin D., MacMillan, David W. C.
Formáid: Artigo
Teanga:Inglês
Foilsithe: 2013
Ábhair:
Rochtain Ar Líne:https://ncbi.nlm.nih.gov/pmc/articles/PMC3667606/
https://ncbi.nlm.nih.gov/pubmed/23586842
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja402933s
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