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Eight-Step Enantioselective Total Synthesis of (−)-Cycloclavine
The first enantioselective total synthesis of (−)-cycloclavine has been accomplished in 8 steps and 7.1% overall yield. Key features include the first catalytic asymmetric cyclopropanation of allene, mediated by dirhodium catalyst Rh(2)(S-TBPTTL)(4), and the enone 1,2-addition of a new TEMPO-carbama...
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| Publicado no: | Angew Chem Int Ed Engl |
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| Main Authors: | , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2016
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC5195887/ https://ncbi.nlm.nih.gov/pubmed/27860203 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201608820 |
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