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Total Synthesis of (±)-Cycloclavine and (±)-5-epi-Cycloclavine

Novel routes to the naturally occurring indole alkaloid cycloclavine and its unnatural C(5)-epimer are described. Key features include the rapid construction of the heterocyclic core segments by two Diels-Alder reactions. An indole annulation was accomplished by a late-stage intramolecular Diels-Ald...

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Sonraí Bibleagrafaíochta
Main Authors: Petronijevic, Filip R., Wipf, Peter
Formáid: Artigo
Teanga:Inglês
Foilsithe: 2011
Ábhair:
Rochtain Ar Líne:https://ncbi.nlm.nih.gov/pmc/articles/PMC3111057/
https://ncbi.nlm.nih.gov/pubmed/21517102
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja2026882
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