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Total synthesis of (−)-sessilifoliamide C and (−)-8-epi-stemoamide

[Image: see text] A convergent route featuring [3,3]-sigmatropic rearrangements of a linchpin azepinopyrrolidine served to install two of the four contiguous stereocenters present in the tricyclic Stemona alkaloids sessilifoliamide and stemoamide. In addition to the first total synthesis of (−)-sess...

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Detalhes bibliográficos
Main Authors: Hoye, Adam T., Wipf, Peter
Formato: Artigo
Idioma:Inglês
Publicado em: 2011
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC3099051/
https://ncbi.nlm.nih.gov/pubmed/21510628
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ol200743u
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