Theoretical Aspects of Orbital Steering
A calculation based on transition-state theory leads to the conclusion that rate accelerations of 10(3)-10(5) could be achieved in an optimally oriented reaction relative to a similar randomly oriented bimolecular reaction. This factor is obtained by the use of partition functions of simplified syst...
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| Udgivet i: | Proc Natl Acad Sci U S A |
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| Principais autores: | , |
| Format: | Artigo |
| Sprog: | Inglês |
| Udgivet: |
National Academy of Sciences
1971
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| Fag: | |
| Online adgang: | https://ncbi.nlm.nih.govhttps://pmc.ncbi.nlm.nih.gov/articles/PMC389444/ https://ncbi.nlm.nih.govhttps://pubmed.ncbi.nlm.nih.gov/5289878/ https://ncbi.nlm.nih.govhttps://doi.org/10.1073/pnas.68.10.2463 |
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