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On the Concept of Orbital Steering in Catalytic Reactions
Angular displacement from linear overlap of but a few degrees in the transition state of the enzyme-substrate complex has been postulated to be of great kinetic significance (“orbital steering”). The concept of orbital steering is shown to have evolved from the orientation parameters of an equation...
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| Main Authors: | , , |
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| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
1971
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC389011/ https://ncbi.nlm.nih.gov/pubmed/16591915 |
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