On the Concept of Orbital Steering in Catalytic Reactions
Angular displacement from linear overlap of but a few degrees in the transition state of the enzyme-substrate complex has been postulated to be of great kinetic significance (“orbital steering”). The concept of orbital steering is shown to have evolved from the orientation parameters of an equation...
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| Gepubliceerd in: | Proc Natl Acad Sci U S A |
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| Hoofdauteurs: | , , |
| Formaat: | Artigo |
| Taal: | Inglês |
| Gepubliceerd in: |
National Academy of Sciences
1971
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| Onderwerpen: | |
| Online toegang: | https://ncbi.nlm.nih.govhttps://pmc.ncbi.nlm.nih.gov/articles/PMC389011/ https://ncbi.nlm.nih.govhttps://pubmed.ncbi.nlm.nih.gov/16591915/ https://ncbi.nlm.nih.govhttps://doi.org/10.1073/pnas.68.3.658 |
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