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Theoretical Aspects of Orbital Steering

A calculation based on transition-state theory leads to the conclusion that rate accelerations of 10(3)-10(5) could be achieved in an optimally oriented reaction relative to a similar randomly oriented bimolecular reaction. This factor is obtained by the use of partition functions of simplified syst...

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Detalhes bibliográficos
Main Authors: Dafforn, A., Koshland, D. E.
Formato: Artigo
Idioma:Inglês
Publicado em: 1971
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC389444/
https://ncbi.nlm.nih.gov/pubmed/5289878
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