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Correlation of Electronic and Geometric Structure in Mononuclear Copper(II) Superoxide Complexes

The geometry of mononuclear copper(II) superoxide complexes has been shown to determine their ground state where side-on bonding leads to a singlet ground state and end-on complexes have triplet ground states. In apparent contrast to this trend, the recently synthesized (HIPT(3)tren)Cu(II)–O(2)(•−)...

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Detalhes bibliográficos
Main Authors: Ginsbach, Jake W., Peterson, Ryan L., Cowley, Ryan E., Karlin, Kenneth D., Solomon, Edward I.
Formato: Artigo
Idioma:Inglês
Publicado em: 2013
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC3882273/
https://ncbi.nlm.nih.gov/pubmed/24164429
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ic402357u
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