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An Anionic, Tetragonal Copper(II) Superoxide Complex

Insight into copper-oxygen species proposed as intermediates in oxidation catalysis is provided by the identification of a Cu(II)-superoxide complex supported by a sterically hindered, pyridinedicarboxamide ligand. A tetragonal, end-on superoxide structure is proposed based on DFT calculations and U...

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Detalhes bibliográficos
Main Authors: Donoghue, Patrick J., Gupta, Aalo K., Boyce, David W., Cramer, Christopher J., Tolman, William B.
Formato: Artigo
Idioma:Inglês
Publicado em: 2010
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC3013377/
https://ncbi.nlm.nih.gov/pubmed/20977226
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja106244k
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