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Revisiting the Synthesis and Nucleophilic Reactivity of an Anionic Copper Superoxide Complex

The addition of 1 equiv of KO(2) and Kryptofix222 (Krypt) in CH(3)CN to a solution of LCu(CH(3)CN) [L = N,N′-bis(2,6-diisopropylphenyl)-2,6-pyridinecarboxamide] in tetrahydrofuran at −80 °C yielded [K(Krypt)][LCuO(2)], the enhanced stability of which enabled reexamination of its reactivity with 2-ph...

詳細記述

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書誌詳細
出版年:Inorg Chem
主要な著者: Bailey, Wilson D., Gagnon, Nicole L., Elwell, Courtney E., Cramblitt, Anna C., Bouchey, Caitlin J., Tolman, William B.
フォーマット: Artigo
言語:Inglês
出版事項: 2019
主題:
オンライン・アクセス:https://ncbi.nlm.nih.gov/pmc/articles/PMC6548509/
https://ncbi.nlm.nih.gov/pubmed/30901201
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acs.inorgchem.9b00090
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