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Mechanistic Dichotomy in Proton-Coupled Electron-Transfer Reactions of Phenols with a Copper Superoxide Complex
The kinetics and mechanism(s) of the reactions of [K(Krypt)][LCuO(2)] (Krypt = 4,7,13,16,21,24-hexaoxa-1,10- diazabicyclo[8.8.8]hexacosane, L = a bis(arylcarboxamido)- pyridine ligand) with 2,2,6,6-tetramethylpiperdine-N-hydroxide (TEMPOH) and the para-substituted phenols (X)ArOH (X = para substitue...
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| Pubblicato in: | J Am Chem Soc |
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| Autori principali: | , , , |
| Natura: | Artigo |
| Lingua: | Inglês |
| Pubblicazione: |
2019
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| Soggetti: | |
| Accesso online: | https://ncbi.nlm.nih.gov/pmc/articles/PMC6584633/ https://ncbi.nlm.nih.gov/pubmed/30907590 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.9b00466 |
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