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Proton-coupled electron transfer: the mechanistic underpinning for radical transport and catalysis in biology
Charge transport and catalysis in enzymes often rely on amino acid radicals as intermediates. The generation and transport of these radicals are synonymous with proton-coupled electron transfer (PCET), which intrinsically is a quantum mechanical effect as both the electron and proton tunnel. The cav...
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| Hauptverfasser: | , , , |
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| Format: | Artigo |
| Sprache: | Inglês |
| Veröffentlicht: |
The Royal Society
2006
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| Schlagworte: | |
| Online Zugang: | https://ncbi.nlm.nih.gov/pmc/articles/PMC1647304/ https://ncbi.nlm.nih.gov/pubmed/16873123 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1098/rstb.2006.1874 |
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