Proton-coupled electron transfer: the mechanistic underpinning for radical transport and catalysis in biology

Charge transport and catalysis in enzymes often rely on amino acid radicals as intermediates. The generation and transport of these radicals are synonymous with proton-coupled electron transfer (PCET), which intrinsically is a quantum mechanical effect as both the electron and proton tunnel. The cav...

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Hauptverfasser: Reece, Steven Y, Hodgkiss, Justin M, Stubbe, JoAnne, Nocera, Daniel G
Format: Artigo
Sprache:Inglês
Veröffentlicht: The Royal Society 2006
Schlagworte:
Research Article
Online Zugang:https://ncbi.nlm.nih.gov/pmc/articles/PMC1647304/
https://ncbi.nlm.nih.gov/pubmed/16873123
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1098/rstb.2006.1874
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