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Nickel/Bis(oxazoline)-Catalyzed Asymmetric Negishi Arylations of Racemic Secondary Benzylic Electrophiles to Generate Enantioenriched 1,1-Diaryalkanes
A tertiary stereogenic center that bears two different aryl substituents is found in a variety of bioactive compounds, including medicines such as Zoloft(™) and Detrol(™). We have developed an efficient method for the synthesis of enantioenriched 1,1-diarylalkanes from readily available racemic benz...
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| 主要な著者: | , , |
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| フォーマット: | Artigo |
| 言語: | Inglês |
| 出版事項: |
2013
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| 主題: | |
| オンライン･アクセス: | https://ncbi.nlm.nih.gov/pmc/articles/PMC3869004/ https://ncbi.nlm.nih.gov/pubmed/24164502 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja408561b |
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