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Stereoconvergent Negishi Arylations of Racemic Secondary Alkyl Electrophiles: Differentiating Between a CF(3) and an Alkyl Group
In this report, we establish that a readily available nickel/bis(oxazoline) catalyst accomplishes a wide array of enantioconvergent cross-couplings of arylzinc reagents with CF(3)-substituted racemic secondary alkyl halides, a process that necessitates that the chiral catalyst be able to effectively...
Wedi'i Gadw mewn:
| Cyhoeddwyd yn: | J Am Chem Soc |
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| Prif Awduron: | , |
| Fformat: | Artigo |
| Iaith: | Inglês |
| Cyhoeddwyd: |
2015
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| Pynciau: | |
| Mynediad Ar-lein: | https://ncbi.nlm.nih.gov/pmc/articles/PMC4610818/ https://ncbi.nlm.nih.gov/pubmed/26203662 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.5b04725 |
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