Загрузка...

Enantioconvergent Cross-Couplings of Racemic Alkylmetal Reagents with Unactivated Secondary Alkyl Electrophiles: Catalytic Asymmetric Negishi α-Alkylations of N-Boc-pyrrolidine

Although enantioconvergent alkyl-alkyl couplings of racemic electrophiles have been developed, there have been no reports of the corresponding reactions of racemic nucleophiles. Herein, we describe Negishi cross-couplings of racemic α-zincated N-Boc-pyrrolidine with unactivated secondary halides, th...

Полное описание

Сохранить в:
Библиографические подробности
Главные авторы: Cordier, Christopher J., Lundgren, Rylan J., Fu, Gregory C.
Формат: Artigo
Язык:Inglês
Опубликовано: 2013
Предметы:
Online-ссылка:https://ncbi.nlm.nih.gov/pmc/articles/PMC3803154/
https://ncbi.nlm.nih.gov/pubmed/23869442
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja4054114
Метки: Добавить метку
Нет меток, Требуется 1-ая метка записи!