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An n→π* Interaction Reduces the Electrophilicity of the Acceptor Carbonyl Group
Carbonyl–carbonyl (C=O···C′=O′) interactions are ubiquitous in both small and large molecular systems. This interaction involves delocalization of a lone pair (n) of a donor oxygen into the antibonding orbital (π*) of an acceptor carbonyl group. Analyses of high-resolution protein structures suggest...
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| Главные авторы: | , , , |
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| Формат: | Artigo |
| Язык: | Inglês |
| Опубликовано: |
2013
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| Предметы: | |
| Online-ссылка: | https://ncbi.nlm.nih.gov/pmc/articles/PMC3840071/ https://ncbi.nlm.nih.gov/pubmed/23928794 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c3cc44573a |
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