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Signature of n→π* interactions in α-helices

The oxygen of a peptide bond has two lone pairs of electrons. One of these lone pairs is poised to interact with the electron-deficient carbon of the subsequent peptide bond in the chain. Any partial covalency that results from this n→π* interaction should induce pyramidalization of the carbon (C′(i...

詳細記述

保存先:
書誌詳細
主要な著者: Choudhary, Amit, Raines, Ronald T
フォーマット: Artigo
言語:Inglês
出版事項: Wiley Subscription Services, Inc., A Wiley Company 2011
主題:
オンライン・アクセス:https://ncbi.nlm.nih.gov/pmc/articles/PMC3104237/
https://ncbi.nlm.nih.gov/pubmed/21442680
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/pro.627
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