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An n→π(*) Interaction in Aspirin: Implications for Structure and Reactivity
Stereoelectronic effects modulate molecular structure, reactivity, and conformation. We find that the interaction between the ester and carboxyl moieties of aspirin has a previously unappreciated quantum mechanical character that arises from the delocalization of an electron pair (n) of a donor grou...
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| 主要な著者: | , , |
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| フォーマット: | Artigo |
| 言語: | Inglês |
| 出版事項: |
2011
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| 主題: | |
| オンライン･アクセス: | https://ncbi.nlm.nih.gov/pmc/articles/PMC3184772/ https://ncbi.nlm.nih.gov/pubmed/21842865 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jo201389d |
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