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Stabilities of Uracil and Pyridone-Based Carbanions: A Systematic Study in the Gas Phase and Solution and Implications for the Mechanism of Orotidine-5′-Monophosphate Decarboxylase

The stabilities of the C6-centered carbanions derived from 1,3-dimethyluracil, N-methyl-2-pyridone, and N-methyl-4-pyridone were systematically investigated in the gas phase and in DMSO and water solutions. The stabilities of the carbanions in the gas phase and DMSO were directly measured through th...

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Autors principals: Senger, Nicholas A., Bliss, Carly E., Keeffe, James R., Gronert, Scott, Wu, Weiming
Format: Artigo
Idioma:Inglês
Publicat: 2013
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Accés en línia:https://ncbi.nlm.nih.gov/pmc/articles/PMC3780433/
https://ncbi.nlm.nih.gov/pubmed/24072938
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1016/j.tet.2013.05.003
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