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The Stability of 6-Carbanion of Uracil Analogues: Mechanistic Implications for Model Reactions of Orotidine-5’-Monophosphate Decarboxylas
[Image: see text] The pK(a)’s of the 6–CH groups of N-methyl-2-pyridone and N-methyl-4-pyridone in aqueous solution were determined. No correlation between the stability of the carbanions and the rate of decarboxylation of corresponding carboxylic acids was found.
Gorde:
| Egile Nagusiak: | , , |
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| Formatua: | Artigo |
| Hizkuntza: | Inglês |
| Argitaratua: |
2006
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| Gaiak: | |
| Sarrera elektronikoa: | https://ncbi.nlm.nih.gov/pmc/articles/PMC2743169/ https://ncbi.nlm.nih.gov/pubmed/17165919 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ol0624981 |
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