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The Stability of 6-Carbanion of Uracil Analogues: Mechanistic Implications for Model Reactions of Orotidine-5’-Monophosphate Decarboxylas

[Image: see text] The pK(a)’s of the 6–CH groups of N-methyl-2-pyridone and N-methyl-4-pyridone in aqueous solution were determined. No correlation between the stability of the carbanions and the rate of decarboxylation of corresponding carboxylic acids was found.

Gorde:
Xehetasun bibliografikoak
Egile Nagusiak: Wong, Freeman M., Capule, Christina, Wu, Weiming
Formatua: Artigo
Hizkuntza:Inglês
Argitaratua: 2006
Gaiak:
Sarrera elektronikoa:https://ncbi.nlm.nih.gov/pmc/articles/PMC2743169/
https://ncbi.nlm.nih.gov/pubmed/17165919
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ol0624981
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