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Nucleophilic addition to silyl-protected five-membered ring oxocarbenium ions governed by stereoelectronic effects
A series of fused-bicyclic acetals containing a disiloxane ring was investigated to evaluate the source of selectivity in silyl-protected 2-deoxyribose systems. The disiloxane ring unexpectedly enables the diaxial conformer of the cation to be stabilized by an electronegative atom at C-3. This low e...
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| 主要な著者: | , |
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| フォーマット: | Artigo |
| 言語: | Inglês |
| 出版事項: |
2013
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| 主題: | |
| オンライン･アクセス: | https://ncbi.nlm.nih.gov/pmc/articles/PMC3713616/ https://ncbi.nlm.nih.gov/pubmed/23738497 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jo400945j |
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