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Stereoelectronic Model to Explain Highly Stereoselective Reactions of Seven-membered Ring Oxocarbenium Ion Intermediates
Nucleophilic attack on seven-membered ring oxocarbenium ions is generally highly stereoselective. The preferred mode of nucleophilic attack forms the product in a conformation that minimizes transannular interactions, leading to different stereoselectivities compared to reactions involving six-membe...
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| Опубликовано в: : | Angew Chem Int Ed Engl |
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| Главные авторы: | , , , |
| Формат: | Artigo |
| Язык: | Inglês |
| Опубликовано: |
2016
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| Предметы: | |
| Online-ссылка: | https://ncbi.nlm.nih.gov/pmc/articles/PMC4811184/ https://ncbi.nlm.nih.gov/pubmed/26791884 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201507806 |
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