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Stereoelectronic Model to Explain Highly Stereoselective Reactions of Seven-membered Ring Oxocarbenium Ion Intermediates

Nucleophilic attack on seven-membered ring oxocarbenium ions is generally highly stereoselective. The preferred mode of nucleophilic attack forms the product in a conformation that minimizes transannular interactions, leading to different stereoselectivities compared to reactions involving six-membe...

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Publicado en:Angew Chem Int Ed Engl
Main Authors: Beaver, Matthew G., Buscagan, Trixia M., Lavinda, Olga, Woerpel, K. A.
Formato: Artigo
Idioma:Inglês
Publicado: 2016
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Acceso en liña:https://ncbi.nlm.nih.gov/pmc/articles/PMC4811184/
https://ncbi.nlm.nih.gov/pubmed/26791884
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201507806
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