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An oxocarbenium-ion intermediate of a ribozyme reaction indicated by kinetic isotope effects
Many of the enzymes that catalyze reactions at nucleotide glycosidic linkages proceed through either a reactive oxocarbenium-ion intermediate or a transition state with considerable oxocarbenium character. To investigate how an RNA active site deals with the catalytic challenge of nucleotide synthes...
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| Main Authors: | , |
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| Format: | Artigo |
| Jezik: | Inglês |
| Izdano: |
National Academy of Sciences
2003
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| Teme: | |
| Online dostop: | https://ncbi.nlm.nih.gov/pmc/articles/PMC307578/ https://ncbi.nlm.nih.gov/pubmed/14668444 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1073/pnas.2433147100 |
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