A carregar...
Nucleophilic addition to silyl-protected five-membered ring oxocarbenium ions governed by stereoelectronic effects
A series of fused-bicyclic acetals containing a disiloxane ring was investigated to evaluate the source of selectivity in silyl-protected 2-deoxyribose systems. The disiloxane ring unexpectedly enables the diaxial conformer of the cation to be stabilized by an electronegative atom at C-3. This low e...
Na minha lista:
Main Authors: | , |
---|---|
Formato: | Artigo |
Idioma: | Inglês |
Publicado em: |
2013
|
Assuntos: | |
Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC3713616/ https://ncbi.nlm.nih.gov/pubmed/23738497 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jo400945j |
Tags: |
Adicionar Tag
Sem tags, seja o primeiro a adicionar uma tag!
|
A carregar...