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Nucleophilic addition to silyl-protected five-membered ring oxocarbenium ions governed by stereoelectronic effects
A series of fused-bicyclic acetals containing a disiloxane ring was investigated to evaluate the source of selectivity in silyl-protected 2-deoxyribose systems. The disiloxane ring unexpectedly enables the diaxial conformer of the cation to be stabilized by an electronegative atom at C-3. This low e...
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| Main Authors: | , |
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| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2013
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC3713616/ https://ncbi.nlm.nih.gov/pubmed/23738497 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jo400945j |
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