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Swain–Scott Relationships for Nucleophile Addition to Ring-Substituted Phenonium Ions
The products of the reactions of 2-(4-methoxyphenyl)ethyl tosylate (MeO-1-Ts) and 2-(4-methyphenyl)ethyl tosylate (Me-1-Ts) with nucleophilic anions were determined for reactions in 50/50 (v/v) trifluoroethanol/water at 25°C. In many cases the nucleophile selectivity k(Nu)/k(s) (M(−1)) for reactions...
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| Udgivet i: | Can J Chem |
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| Main Authors: | , |
| Format: | Artigo |
| Sprog: | Inglês |
| Udgivet: |
2014
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| Fag: | |
| Online adgang: | https://ncbi.nlm.nih.gov/pmc/articles/PMC4734394/ https://ncbi.nlm.nih.gov/pubmed/26843657 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1139/cjc-2014-0337 |
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