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Enantioselective Redox-Relay Oxidative Heck Arylations of Acyclic Alkenyl Alcohols using Boronic Acids

A general, highly selective asymmetric redox-relay oxidative Heck reaction using achiral or racemic acyclic alkenols and boronic acid derivatives is reported. This reaction delivers remotely functionalized arylated carbonyl products from acyclic alkenol substrates, with excellent enantioselectivity...

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Detalhes bibliográficos
Main Authors: Mei, Tian-Sheng, Werner, Erik W., Burckle, Alexander J., Sigman, Matthew S.
Formato: Artigo
Idioma:Inglês
Publicado em: 2013
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC3698857/
https://ncbi.nlm.nih.gov/pubmed/23607624
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja402916z
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