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Enantioselective Redox-Relay Oxidative Heck Arylations of Acyclic Alkenyl Alcohols using Boronic Acids

A general, highly selective asymmetric redox-relay oxidative Heck reaction using achiral or racemic acyclic alkenols and boronic acid derivatives is reported. This reaction delivers remotely functionalized arylated carbonyl products from acyclic alkenol substrates, with excellent enantioselectivity...

Ausführliche Beschreibung

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Bibliographische Detailangaben
Hauptverfasser: Mei, Tian-Sheng, Werner, Erik W., Burckle, Alexander J., Sigman, Matthew S.
Format: Artigo
Sprache:Inglês
Veröffentlicht: 2013
Schlagworte:
Online Zugang:https://ncbi.nlm.nih.gov/pmc/articles/PMC3698857/
https://ncbi.nlm.nih.gov/pubmed/23607624
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja402916z
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