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Enantioselective Redox-Relay Oxidative Heck Arylations of Acyclic Alkenyl Alcohols using Boronic Acids

A general, highly selective asymmetric redox-relay oxidative Heck reaction using achiral or racemic acyclic alkenols and boronic acid derivatives is reported. This reaction delivers remotely functionalized arylated carbonyl products from acyclic alkenol substrates, with excellent enantioselectivity...

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Détails bibliographiques
Auteurs principaux: Mei, Tian-Sheng, Werner, Erik W., Burckle, Alexander J., Sigman, Matthew S.
Format: Artigo
Langue:Inglês
Publié: 2013
Sujets:
Accès en ligne:https://ncbi.nlm.nih.gov/pmc/articles/PMC3698857/
https://ncbi.nlm.nih.gov/pubmed/23607624
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja402916z
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