Successive C-C Coupling of Dienes to Vicinally Dioxygenated Hydrocarbons: Ruthenium Catalyzed [4+2] Cycloaddition across the Diol, Hydroxycarbonyl or Dione Oxidation Levels

The ruthenium(0) catalyst generated from Ru(3)(CO)(12) and tricyclohexylphosphine or BIPHEP promotes successive C-C coupling of dienes to vicinally dioxygenated hydrocarbons across the diol, hydroxyketone and dione oxidation levels to form products of [4+2] cycloaddition. A mechanism involving diene...

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Autores principales: Geary, Laina M., Glasspoole, Ben W., Kim, Mary M., Krische, Michael J.
Formato: Artigo
Lenguaje:Inglês
Publicado: 2013
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Article
Acceso en línea:https://ncbi.nlm.nih.gov/pmc/articles/PMC3607350/
https://ncbi.nlm.nih.gov/pubmed/23448269
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja400691t
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