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Diols as Dienophiles: Bridged Carbocycles via Ruthenium(0) Catalyzed Transfer Hydrogenative Cycloadditions of Cyclohexadiene or Norbornadiene()
Highlyexo-selective ruthenium(0) catalyzed transfer hydrogenative cycloadditions of 1,2-diols with cyclohexadiene or norbornadiene are described. Novel bridged bicyclic ring systems are accessible from the diol, α-ketol or 1,2-dione oxidation levels with complete control of diastereoselectivity. [Im...
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| Veröffentlicht in: | Angew Chem Int Ed Engl |
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| Hauptverfasser: | , , , |
| Format: | Artigo |
| Sprache: | Inglês |
| Veröffentlicht: |
2017
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| Schlagworte: | |
| Online Zugang: | https://ncbi.nlm.nih.gov/pmc/articles/PMC5677533/ https://ncbi.nlm.nih.gov/pubmed/28941001 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201708189 |
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