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Successive C-C Coupling of Dienes to Vicinally Dioxygenated Hydrocarbons: Ruthenium Catalyzed [4+2] Cycloaddition across the Diol, Hydroxycarbonyl or Dione Oxidation Levels
The ruthenium(0) catalyst generated from Ru(3)(CO)(12) and tricyclohexylphosphine or BIPHEP promotes successive C-C coupling of dienes to vicinally dioxygenated hydrocarbons across the diol, hydroxyketone and dione oxidation levels to form products of [4+2] cycloaddition. A mechanism involving diene...
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| Main Authors: | , , , |
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| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2013
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC3607350/ https://ncbi.nlm.nih.gov/pubmed/23448269 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja400691t |
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