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Ruthenium Catalyzed Hydrohydroxyalkylation of Acrylates with Diols and α-Hydroxycarbonyl Compounds to Form Spiro- and α-Methylene-γ-Butyrolactones

Under the conditions of ruthenium(0) catalyzed hydrohydroxyalkylation, vicinal diols 1a–1l and methyl acrylate 2a are converted to the corresponding lactones 3a–3l in good to excellent yield. The reaction of methyl acrylate 2a with hydrobenzoin 1f, benzoin didehydro-1f, and benzil tetradehydro-1f fo...

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Bibliografski detalji
Glavni autori: McInturff, Emma L., Mowat, Jeffrey, Waldeck, Andrew R., Krische, Michael J.
Format: Artigo
Jezik:Inglês
Izdano: 2013
Teme:
Online pristup:https://ncbi.nlm.nih.gov/pmc/articles/PMC3873753/
https://ncbi.nlm.nih.gov/pubmed/24187991
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja410533y
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