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A new intermediate in the Prins reaction
Two Prins reactions were investigated by the use of DFT calculations. A model composed of R–CH=CH(2) + H(3)O(+)(H(2)O)(13) + (H(2)C=O)(2), R = Me and Ph, was adopted to trace reaction paths. For both alkenes, the concerted path forming 1,3-diols was obtained as the rate determining step (TS1). TS st...
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| Asıl Yazarlar: | , , |
|---|---|
| Materyal Türü: | Artigo |
| Dil: | Inglês |
| Baskı/Yayın Bilgisi: |
Beilstein-Institut
2013
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| Konular: | |
| Online Erişim: | https://ncbi.nlm.nih.gov/pmc/articles/PMC3596789/ https://ncbi.nlm.nih.gov/pubmed/23532354 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.3762/bjoc.9.51 |
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