A carregar...

Racemization in Prins Cyclization Reactions

Isotopic labeling experiments were performed in order to elucidate a new mechanism for racemization in Prins cyclization reactions. The loss in optical activity for these reactions was shown to occur by 2-oxonia-Cope rearrangements by way of a (Z)-oxocarbenium ion intermediate. Reaction conditions s...

ver descrição completa

Na minha lista:
Detalhes bibliográficos
Main Authors: Jasti, Ramesh, Rychnovsky, Scott D.
Formato: Artigo
Idioma:Inglês
Publicado em: 2006
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC2483253/
https://ncbi.nlm.nih.gov/pubmed/17031979
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja064783l
Tags: Adicionar Tag
Sem tags, seja o primeiro a adicionar uma tag!