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Racemization in Prins Cyclization Reactions
Isotopic labeling experiments were performed in order to elucidate a new mechanism for racemization in Prins cyclization reactions. The loss in optical activity for these reactions was shown to occur by 2-oxonia-Cope rearrangements by way of a (Z)-oxocarbenium ion intermediate. Reaction conditions s...
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| Main Authors: | , |
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| Format: | Artigo |
| Sprog: | Inglês |
| Udgivet: |
2006
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| Fag: | |
| Online adgang: | https://ncbi.nlm.nih.gov/pmc/articles/PMC2483253/ https://ncbi.nlm.nih.gov/pubmed/17031979 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja064783l |
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