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β,γ-CHF- and β,γ-CHCl-dGTP diastereomers: synthesis, discrete (31)P NMR signatures and absolute configurations of new stereochemical probes for DNA polymerases
Deoxynucleoside 5′-triphosphate analogues in which the β,γ-bridging oxygen has been replaced with a CXY group are useful chemical probes to investigate DNA polymerase catalytic and base selection mechanisms. A limitation of such probes has been that conventional synthetic methods generate a mixture...
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| Main Authors: | , , , , , , |
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| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2012
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC3595068/ https://ncbi.nlm.nih.gov/pubmed/22397499 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja300218x |
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