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Nickel-Catalyzed Reductive Conjugate Addition to Enones Via Allylnickel Intermediates
An alternative method to copper-catalyzed conjugate addition followed by enolate silylation for the synthesis of β-di-substituted silyl enol ether products (R(1)(R(2))HCCH=C(OSiR(4)(3))R(3)) is presented. This method uses haloarenes instead of nucleophilic aryl reagents. Nickel ligated to either neo...
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| Autores principales: | , , |
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| Formato: | Artigo |
| Lenguaje: | Inglês |
| Publicado: |
2013
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| Materias: | |
| Acceso en línea: | https://ncbi.nlm.nih.gov/pmc/articles/PMC3547151/ https://ncbi.nlm.nih.gov/pubmed/23270480 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja309176h |
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