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Nickel-catalyzed reductive arylation of activated alkynes with aryl iodides

The direct, regioselective, and stereoselective arylation of activated alkynes with aryl iodides using a nickel catalyst and manganese reductant is described. The reaction conditions are mild (40 °C in MeOH, no acid or base) and an intermediate organomanganese reagent is unlikely. Functional groups...

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Detalhes bibliográficos
Publicado no:Tetrahedron Lett
Main Authors: Dorn, Stephanie C. M., Olsen, Andrew K, Kelemen, Rachel E., Shrestha, Ruja, Weix, Daniel J.
Formato: Artigo
Idioma:Inglês
Publicado em: 2015
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC4446700/
https://ncbi.nlm.nih.gov/pubmed/26028781
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1016/j.tetlet.2015.02.120
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