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Nickel-catalyzed reductive arylation of activated alkynes with aryl iodides

The direct, regioselective, and stereoselective arylation of activated alkynes with aryl iodides using a nickel catalyst and manganese reductant is described. The reaction conditions are mild (40 °C in MeOH, no acid or base) and an intermediate organomanganese reagent is unlikely. Functional groups...

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Bibliographic Details
Published in:Tetrahedron Lett
Main Authors: Dorn, Stephanie C. M., Olsen, Andrew K, Kelemen, Rachel E., Shrestha, Ruja, Weix, Daniel J.
Format: Artigo
Language:Inglês
Published: 2015
Subjects:
Online Access:https://ncbi.nlm.nih.gov/pmc/articles/PMC4446700/
https://ncbi.nlm.nih.gov/pubmed/26028781
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1016/j.tetlet.2015.02.120
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