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Nickel-Catalyzed Reductive [2+2] Cycloaddition of Alkynes
The nickel-catalyzed synthesis of tetrasubstituted cyclobutenes from alkynes is reported. This transformation is uniquely promoted by the use of a primary aminophosphine, an unusual ligand in nickel catalysis. Mechanistic insights for this new transformation are provided, and post-reaction modificat...
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| Published in: | J Am Chem Soc |
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| Main Authors: | , , |
| Format: | Artigo |
| Language: | Inglês |
| Published: |
2018
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| Subjects: | |
| Online Access: | https://ncbi.nlm.nih.gov/pmc/articles/PMC6470007/ https://ncbi.nlm.nih.gov/pubmed/30517785 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.8b09677 |
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