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Synthetic Studies and Mechanistic Insight in Nickel-Catalyzed [4+2+1] Cycloadditions
A new nickel-catalyzed procedure for the [4+2+1] cycloaddition of (trimethylsilyl)diazomethane with alkynes tethered to dienes has been developed. A broad range of unsaturated substrates participates in the sequence, and stereoselectivities are generally excellent. Stereochemical studies provided ev...
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| Autors principals: | , |
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| Format: | Artigo |
| Idioma: | Inglês |
| Publicat: |
2006
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| Matèries: | |
| Accés en línia: | https://ncbi.nlm.nih.gov/pmc/articles/PMC2720272/ https://ncbi.nlm.nih.gov/pubmed/16492045 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja057741q |
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