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Mechanistic Study of Nickel-Catalyzed Ynal Reductive Cyclizations Through Kinetic Analysis

The mechanism of nickel-catalyzed, silane-mediated reductive cyclization of ynals has been evaluated. The cyclizations are first-order in [Ni] and [ynal] and zeroth-order in [silane]. These results, in combination with the lack of rapid silane consumption upon reaction initiation are inconsistent wi...

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Detalhes bibliográficos
Main Authors: Baxter, Ryan D., Montgomery, John
Formato: Artigo
Idioma:Inglês
Publicado em: 2011
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC3083823/
https://ncbi.nlm.nih.gov/pubmed/21438642
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja200867d
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