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Removal of the 20-methyl group from 2-methylene-19-nor-(20S)-1α,25-dihydroxyvitamin D(3) (2MD) selectively eliminates bone calcium mobilization activity

The 18-nor (7), 21-nor (8) and 18,21-dinor (9) analogs of (20S)-1α,25-dihydroxy-2-methylene-19-norvitamin D(3) (6, 2MD) were prepared by convergent syntheses. The known phosphine oxide 10 was coupled by the Wittig–Horner process with the corresponding C,D-fragments (13–15), obtained by a multi-step...

Πλήρης περιγραφή

Αποθηκεύτηκε σε:
Λεπτομέρειες βιβλιογραφικής εγγραφής
Κύριοι συγγραφείς: Barycki, Rafal, Sicinski, Rafal R., Plum, Lori A., Grzywacz, Pawel, Clagett-Dame, Margaret, DeLuca, Hector F.
Μορφή: Artigo
Γλώσσα:Inglês
Έκδοση: 2009
Θέματα:
Διαθέσιμο Online:https://ncbi.nlm.nih.gov/pmc/articles/PMC3539176/
https://ncbi.nlm.nih.gov/pubmed/19819702
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1016/j.bmc.2009.09.047
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