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First Total Synthesis of Jadomycin A and Carbasugar Analogue of Jadomycin B
The first syntheses of Jadomycin A and the carbosugar analogue of Jadomycin B have been achieved in 6 and 20 longest linear steps respectively. The key ring system of the aglycone was prepared by a 6π-electron electrocyclic ring closure and subsequent hemi-aminal ring closure. Acid sensitivity of th...
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| Main Authors: | , , |
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| Format: | Artigo |
| Sprog: | Inglês |
| Udgivet: |
2010
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| Fag: | |
| Online adgang: | https://ncbi.nlm.nih.gov/pmc/articles/PMC3536065/ https://ncbi.nlm.nih.gov/pubmed/20979078 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201005329 |
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