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Protonation of a Peroxodiiron(III) Complex and Conversion to a Diiron(III/IV) Intermediate: Implications for Proton-assisted O-O Bond Cleavage in Nonheme Diiron Enzymes
Oxygenation of a diiron(II) complex,[Fe(II)(2)(μ-OH)(2)(BnBQA)(2)(NCMe)(2)](2+ )(2) (where BnBQA is N-benzyl-N,N-bis(2-quinolinylmethyl)amine) results in the formation of a metastable peroxodiferric intermediate (3). Treatment of 3 with strong acid affords its conjugate acid 4 in which the (μ-oxo)(μ...
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| Autors principals: | , , , , , , , |
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| Format: | Artigo |
| Idioma: | Inglês |
| Publicat: |
2012
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| Matèries: | |
| Accés en línia: | https://ncbi.nlm.nih.gov/pmc/articles/PMC3462276/ https://ncbi.nlm.nih.gov/pubmed/22971084 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ic301642w |
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