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New Preorganized γ-Amino Acids as Foldamer Building Blocks

[Image: see text] An asymmetric synthesis of two new diastereomeric γ-amino acids is described. Both molecules contain a cyclohexyl ring to limit conformational flexibility about the Cα-C(β) bond; they differ in having cis vs. trans stereochemistry on the ring. Residues derived from the cis γ isomer...

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Detalhes bibliográficos
Main Authors: Guo, Li, Zhang, Weicheng, Guzei, Ilia A., Spencer, Lara C., Gellman, Samuel H.
Formato: Artigo
Idioma:Inglês
Publicado em: 2012
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC3445736/
https://ncbi.nlm.nih.gov/pubmed/22568480
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ol3008815
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