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Are Free Radicals Involved in IspH Catalysis? An EPR and Crystallographic Investigation

The [4Fe-4S] protein IspH in the methylerythritol phosphate isoprenoid biosynthesis pathway is an important anti-infective drug target, but its mechanism of action is still the subject of debate. Here, by using electron paramagnetic resonance (EPR) spectroscopy and (2)H, (17)O, and (57)Fe isotopic l...

Ausführliche Beschreibung

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Bibliographische Detailangaben
Hauptverfasser: Wang, Weixue, Wang, Ke, Span, Ingrid, Jauch, Johann, Bacher, Adelbert, Groll, Michael, Oldfield, Eric
Format: Artigo
Sprache:Inglês
Veröffentlicht: 2012
Schlagworte:
Online Zugang:https://ncbi.nlm.nih.gov/pmc/articles/PMC3394908/
https://ncbi.nlm.nih.gov/pubmed/22687151
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja303445z
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